Skeleton structure hydrocarbons in different genetic types of oils and condensates in Western Yakutia
https://doi.org/10.31242/2618-9712-2021-26-4-43-53
Abstract
This work is devoted to the study of the content, composition and character of the distribution of adamantane hydrocarbons. The objects of investigation were naphthides of different genetic types from the deposits in Western Yakutia: oils and condensates from the Vendian-Cambrian sediments, which were generated by planktonic algal organic matter of marine facies (I genotype), and the Mesozoic oils and condensates, which were generated by continental terragenous organic matter (II genotype). The individual hydrocarbon composition of the fractions was determined by chromatography-mass spectrometry on the Agilent 6890 set, which had an interface with the high-effective mass-selective detector Agilent 5973N. The characteristic distribution pattern of adamantane and its methyl derivatives was obtained by scanning for fragmentary m/z ions 135, 136, 149, 163, 177, 188. As a result of the conducted research, the presence of adamantane hydrocarbons of the composition from C10H16 to C14H24 was established for the studied samples of naphthides. It was shown that adamantane hydrocarbons within each genetic type were characterized by a similar composition and distribution. At the same time, certain differences were detected in the distribution of naphthides of different genesis. The naphthides of I genotype (generated by planktonic algal organic matter of marine facies) differed from the naphthides of II genotype (generated by terragenous organic matter of continental facies) by lower content of adamantine and its methyland dimethylpropionic derivatives, a high content of triand tetramethylguanidine, lower values of C11/C13 and C12/C13 ratios, and the values of ethyuladamantane index. The obtained data on the composition of adamantane hydrocarbons can be used as additional geochemical criteria for determination of the genesis of naphthides.
Keywords
adamantane hydrocarbons,
adamantane,
methyladamantane,
gas chromatography-mass spectrometry,
naphthide genotypes,
oils and condensates
Supporting agencies: The research was carried out within the framework of the Fundamental Scientific Research Program (Project number АААА-А21-121011490054-0).
About the Authors
O. N. Chalaya
Institute Problems of Oil and Gas SB RAS
Russian Federation
Russian Federation
CHALAYA, Olga Nikolaevna, Cand. Sci. (Geology and Mineralogy), leading researcher
2 Petrovskogo st., Yakutsk 677980
Researcher ID: J-9329-2018
S. Kh. Lifshits
Institute Problems of Oil and Gas SB RAS
Russian Federation
Russian Federation
LIFSHITS, Sara Khaimovna, Cand. Sci. (Chemistry), leading researcher
2 Petrovskogo st., Yakutsk 677980
Researcher ID: K-1438-2018
V. A. Kashirtsev
Institute Problems of Oil and Gas SB RAS;
Trofimuk Institute of Petroleum Geology and Geophysics SB RAS
Russian Federation
Russian Federation
KASHIRCEV, Vladimir Arkadievich, corresponding member of RAS, Dr. Sci. (Geology and Mineralogy), chief researcher
2 Petrovskogo st., Yakutsk 677980;
3 Akademika Koptyuga ave, Novosibirsk 630090
Researcher ID: N-1655-2014
I. N. Zueva
Institute Problems of Oil and Gas SB RAS
Russian Federation
Russian Federation
ZUEVA, Iraida Nikolaevna, Cand. Sci. (Geology and Mineralogy), leading researcher
2 Petrovskogo st., Yakutsk 677980
Researcher ID: J-9373-2018
Yu. S. Glyaznetsova
Institute Problems of Oil and Gas SB RAS
Russian Federation
Russian Federation
GLYAZETSOVA, Yulia Stanislavovna, Cand. Sci. (Chemistry), head of the laboratory
2 Petrovskogo st., Yakutsk 677980
Researcher ID: J-9714-2018
References
1. Bagrij E.I. Adamantany: Poluchenie, svojstva, primenenie. Moscow: Nauka, 1989. 264 p.
2. Gordadze G.N. Geohimija uglevodorodv karkasnogo stroenija (obzor) // Neftechimija. 2008. Vol. 48, No. 4. P. 243–255.
3. Gordadze G.N., Giruc M.V., Koshelev V.N. Organicheskaja geochimija uglevodorodov. 2012. Moscow: RGU nefti i gaza im. I.M. Gubkina, 2012. Book 1. 392 p.
4. Gordadze G.N., Giruc M.V., Koshelev V.N. Organicheskaja geochimija uglevodorodov. 2013. Moscow: RGU nefti i gaza im. I.M. Gubkina, 2012. Book 2. 303 p.
5. Petrov Al.A. Himija naftenov. Moscow: Nauka, 1971. 388 p.
6. Petrov Al.A. Uglevodorody nefti. Moscow: Nauka, 1984. 263 p.
7. Giruc M.V., Gordadze G.N., Stroeva A.R., Stokolos O.A., Bogatyrev S.O., Koshelev V.N. Generacija uglevodorodv almazopodobnogo stroenija iz biomasssy bakterij // Chimija i tehnologija topliv i masel. 2014. No. 4. P. 15–20.
8. Gordadze G.N., Badmaev Ch.M., Jerdnieva O.G., Koshelev V.N., Giruc M.V. Novyj gomologicheskij rjad adamantanov C11–C17 v produktah termokataliza predshestvennikov nefti // Materialy Vserossijskoj nauchnoj konferencii «Uspehi organichekoj geochimii». 2010. P. 110–111.
9. Gordadze G.N., Kerimov V.Ju., Kuznecov N.B., Giruc M.V., Serov S.G., Gajduk A.V. Issledovanie uglevodorodv-biomarkerov i uglevodorodov almazopodobnogo stroenija rifejskih, vendskih i nizhnekembrijskih otlozhenij Katangskoj sedloviny (juzhnaja chast’ Sibirskoj platformy) // Materialy mezhdunarodnoj nauchno-prakticheskoj konferencii «Novye idei v geologii nefti i gaza». Moscow. 2015. P. 92–96.
10. Kashircev V.A., Nesterov I.I., Melenevskij V.N., Fursenko E.A., Kazakov M.O., Lavrenov A.V. Biomarkery i adamantany v neftjah iz senomanskih otlozhenij severa Zapadnoj Sibiri // Geologija i geofizika. 2013. Vol. 5, No. 8. P. 1227–1235.
11. Giruc M.V., Stroeva A.R., Gadzhiev G.A., Stokolos O.A., Koshelev V.N., Gordadze G.N. Adamantany С11–С13 v biodegradirovannyh i nebiodegradirovannyh kondensatah // Neftechimija. 2014. Vol. 54, No. 1. P. 12–16. DOI: 10.7868/S0028242114010043.
12. Bagrij E.I., Maravin G.B. Adamantansoderzhashhie slozhnye jefiry kak vozmozhnye komponenty termostojkih smazochnyh masel // Neftechimija. 2013. Vol. 53, No. 6. P. 467–472. DOI: 10.7868/S0028242113060026.
13. Peters K.E., Walters C.C., Moldovan J.M. The biomarker guide. New York: Cambridge University Press. 2007. V. 1. 471 p.; V. 2. 684 p.
14. Giruc M.V. Puti genezisa nizkomolekuljarnyh adamantanov i diamantanov v neftjah: Avtoref. diss. ... kand. chim. nauk. Moscow, 2006. 25 p.
15. Giruc M.V., Rusinova G.V., Gordadze G.N. Genercija adamantanov i diamantanov v rezul’tate termicheskogo krekinga vysokomolekuljarnyh nasyshhennyh frakcij neftej raznogo genotipa // Neftechimija. 2006. Vol. 46, No. 4. P. 251–261.
16. Giruc M.V., Gordadze G.N. Generacija adamantanov i diamantanov v rezul’tate termicheskogo krekinga poljarnyh komponentov neftej raznogo genotipa // Neftechimija. 2007. Vol. 47, No. 1. P. 15–25.
17. Giruc M.V. Almazopodobnye uglevodorody v neftjah i modelirovanie processov ih obrazovanija: Diss. ... d-ra chim. nauk. Moscow, 2016. 280 p.
18. Gordadze G.N., Giruc M.V. Sintez uglevodorodov rjada adamantana i diamantana putem vysokotemperaturnogo krekinga vysokomolekuljarnyh n-alkanov // Neftechimija. 2008. V.48. No. 6. P. 412–417.
19. Badmaev Ch.M., Giruc M.V., Jerdineva O.G., Koshelev V.N., Gordadze G.N. Generacija monoalkiladamantanov C11–C17 v rezul’tate kataliza nekotoryh kislorodsoderzhashhih predshestvennikov neftjanyh uglevodorodov // Neftechimija. 2011. Vol. 51, No. 5. P. 337–341.
20. Badmaev Ch.M. Uglevodorody karkasnogo stroenija v neftjah Kalmykii: Avtoref. dis. ... cand. chim. nauk. Moscow, 2012. 25 p.
21. Bagrij E.I., Amosova E.I., Sanin P.I. Vydelenie adamantana iz nekotoryh neftej Balahanskogo i Surahanskogo mestorozhdenij // Neftechimija. 1966. Vol. 6, No. 4. 665 p.
22. Geochimija organicheskogo veshhestva neftegazonosnyh otlozhenij Zapadnoj Jakutii. Novosibirsk: Nauka, 1984. 113 p.
23. Izosimova A.N., Chalaja O.N. Reliktovye uglevodorody v organicheskom veshhestve i neftjah Zapadnoj Jakutii. Novosibirsk: Nauka, 1989. 127 p.
24. Geochimija neftei vostoka Siberskoi platformy. Yakutsk: YNC SO RAN. 2009. 180 p.
25. Petrov Al.A., Golovkina L.S., Rusinova G.V. Massspektry neftjanyh uglevodorodv. Spravochnik (atlas). Pod red. Al.A. Petrova. Moscow: Nedra, 1986. 313 p.
26. Bagrij E.I., Borisov Ju.A., Kolbanovskij Ju.A., Maksimov A.L. Teoreticheskoe izuchenie mehanizma reakcii kataliticheskogo alkilirovanija adamantana produktami krekinga 2,2,4-trimetilpentana // Neftechimija. 2019. Vol. 59, No. 1. P. 64–68. DOI: 10.1134/S0028242119010064.
Review
For citations:
Chalaya O.N., Lifshits S.Kh., Kashirtsev V.A., Zueva I.N., Glyaznetsova Yu.S. Skeleton structure hydrocarbons in different genetic types of oils and condensates in Western Yakutia. Arctic and Subarctic Natural Resources. 2021;26(4):43-53. (In Russ.) https://doi.org/10.31242/2618-9712-2021-26-4-43-53
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