Surface treatment of reinforcing fillers with a mixture of phenylmethane and polybutadiene to increase adhesion with elastomer
https://doi.org/10.31242/2618-9712-2022-27-3-439-449
Abstract
The use of high-modulus fibers with improved technological and operational properties in production of the composite elastomers is an urgent task in Materials Science. The widespread reinforcing fillers are basalt, glass and carbon fibers, which have a high chemical inertness. Therefore, the introduction of these fillers into the elastomer requires an increase of their adhesion to the rubber matrix, which further improves the reliability and durability of the material in operation. This paper presents a method for increasing the adhesion between the adhesive and the substrate due to the surface treatment of reinforcing fabrics with a rubber mixture previously dissolved in phenylmethane (toluene). We investigated the obtained materials for elastic-strength properties, wear resistance, hardness and adhesion. We also studied the microstructure in the volume of the material, the friction surface and the place of delamination. The results of the tensile tests showed a general tendency in increasing of the tensile strength values up to 1.6 times and decreasing of the relative elongation values up to 2 times. The tests for wear resistance showed a decrease in values by 10–20 % for samples with the surface treatment of fabric with a dissolved mixture, along with an increase in their hardness values. Surface treatment of fabrics by proposed method before vulcanization increased adhesion values from 1.2 to 3 times.
Keywords
elastomer,
basalt fiber,
carbon fiber,
glass fiber,
high modulus material,
adhesion,
hybrid material,
composite elastomer
Supporting agencies: This study was supported by the Ministry of Education and Science of the Russian Federation under the State Assignment (project number FSRG-2020-0017 and FWRS-2022-0001).
About the Authors
A. E. Markov
The Yakut Scientific Centre SB RAS
Russian Federation
Russian Federation
MARKOV, Aital Eremeevich, Research Engineer, Researcher ID: ACF-8819-2022
Laboratory of Composite Materials of the Arctic Subarctic, 2 Petrovskogo st., Yakutsk 677000
M. M. Kopyrin
The Yakut Scientific Centre SB RAS
Russian Federation
Russian Federation
KOPYRIN, Mikhail Mikhailovich, Junior Researcher, Researcher ID: AAI-8876-2021
Laboratory of Composite Materials of the Arctic Subarctic, 2 Petrovskogo st., Yakutsk 677000
A. A. Dyakonov
The Yakut Scientific Centre SB RAS;
Ammosov North-Eastern Federal University
Russian Federation
Russian Federation
DYAKONOV, Afanasy Alekseevich, Cand. Sci. (Engineering), Researcher, Researcher ID: E-5710-2014
Laboratory of Composite Materials of the Arctic Subarctic, 2 Petrovskogo st., Yakutsk 677000
Institute of Natural Science, 58 Belinsky st., Yakutsk 677000
A. G. Tuisov
The Yakut Scientific Centre SB RAS
Russian Federation
Russian Federation
TUISOV, Aleksei Gennadevich, Cand. Sci. (Engineering), Senior Researcher, Researcher ID: ABA-4930-2020
Laboratory of Composite Materials of the Arctic Subarctic, 2 Petrovskogo st., Yakutsk 677000
A. A. Okhlopkova
Ammosov North-Eastern Federal University
Russian Federation
Russian Federation
OKHLOPKOVA, Aitalina Alekseevna, Dr. Sci. (Engineering), Professor, Chief Researcher, Researcher ID: A-6594-2014
Institute of Natural Science, 58 Belinsky st., Yakutsk 677000
N. N. Lazareva
Ammosov North-Eastern Federal University
Russian Federation
Russian Federation
LAZAREVA, Nadezhda Nikolaevna, Cand. Sci. (Engineering), Leading Researcher, Head of the Laboratory, Researcher ID: E-5063-2014
Institute of Natural Science, 58 Belinsky st., Yakutsk 677000
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Review
For citations:
Markov A.E., Kopyrin M.M., Dyakonov A.A., Tuisov A.G., Okhlopkova A.A., Lazareva N.N. Surface treatment of reinforcing fillers with a mixture of phenylmethane and polybutadiene to increase adhesion with elastomer. Arctic and Subarctic Natural Resources. 2022;27(3):439-449. (In Russ.) https://doi.org/10.31242/2618-9712-2022-27-3-439-449
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