Development of composite materials based on UHMWPE using carbon and basalt fibers
https://doi.org/10.31242/2618-9712-2024-29-4-661-674
Abstract
In contemporary material’s science, the development of high-strength composite materials derived from polymers represents a significant strategic focus. A promising method to enhance the mechanical properties of these materials involves the incorporation of fibrous fillers as modifiers within the polymer matrix, which markedly improves loadbearing capacity. This research investigates the effects of basalt and carbon fibers on the mechanical and tribological characteristics, and on the structural formation processes in ultra-high molecular weight polyethylene (UHMWPE). The fibrous fillers were introduced into the polymer matrix without prior modification at concentrations of 5, 10, and 20 weight percent. Notably, composites containing 20 weight percent carbon fiber exhibited the most pronounced enhancement in elastic modulus, achieving an impressive increase of 66 %. Additionally, a significant reduction in the coefficient of friction was observed, with a decrease of 65 % relative to the unmodified polymer. Furthermore, the wear rate was found to decrease by 23 %. The addition of both carbon and basalt fibers into UHMWPE led to substantial improvements in tensile strength, with increases of 37 % and 28 %, respectively. Analysis of the friction surfaces of the composites through infrared spectroscopy indicated that neither type of fiber influenced the tribochemical processes during wear. The morphological examination of the friction surfaces suggested that carbon fiber possesses a comparative advantage over basalt, contributing to orientation effects and the formation of a wear-resistant layer. The materials developed in this study hold potential applications in the production of antifriction components, particularly for highly loaded sliding bearing elements in bridge structures.
About the Authors
S. N. DanilovaRussian Federation
Danilova Sakhayana Nikolaevna, Cand. Sci. (Eng.), Senior Researcher
ResearcherID: AAZ-5494-2021, Scopus Author ID: 56433195400
Yakutsk
A. A. Okhlopkova
Russian Federation
Okhlopkova Aitalina Alekseevna, Dr. Sci. (Eng.), Professor, Chief Researcher, Head of the Laboratory
ResearcherID: A-6594-2014, Scopus Author ID: 6701324722
Yakutsk
A. V. Okoneshnikova
Russian Federation
Okoneshnikova Anastasia Vasilievna, Student
Scopus Author ID: 58627381700, SPIN: 7804-9770
Yakutsk
References
1. Artemenko S.E., Kadykova Yu.A. Polymer composite materials based on carbon, basalt, and glass fibres. Fibre Chemistry. 2008;40(1):37–39.
2. Chukov D.I., Zherebtsov D.D., Nematulloev S.G. Investigation of structure and properties of self-reinforced composite materials based on ultra-high molecular weigth polyethylene fibers. Basic Research. 2017;(11-1):145– 150. (In Russ.)
3. Selyutin G.E., Gavrilov Y.Y., Voskresenskaya E.N., et al. Composite materials based on ultrahigh-molecular polyethylene: properties, outlooks for use. Chemistry for Sustainable Development. 2010;18(3):301–314.
4. Wang H., Xu L., Zhang M., et al. More wear‐resistant and ductile UHMWPE composite prepared by the addition of radiation cross-linked UHMWPE powder. Journal of Applied Polymer Science. 2017;134(13):44643. https://doi.org/10.1002/app.44643.
5. Salama A., Kamel B.M., Osman T.A., Rashad R.M. Investigation of mechanical properties of UHMWPE composites reinforced with HAP+ TiO2 fabricated by solvent dispersing technique. Journal of Materials Research and Technology. 2022;21:4330–4343. https://doi.org/10.1016/j.jmrt.2022.11.038.
6. Okhlopkova T.A. Tribotechnical materials based on UHMWPE modified with nanoscale oxide ceramics: Diss. … Cand. Sci, Tomsk; 2018. 156 p. (In Russ.)
7. Danilova S.N., Yarusova S.B., Kulchin Y.N., et al. UHMWPE/CaSiO3 nanocomposite: Mechanical and tribological properties. Polymers. 2021;13(4):570. https://doi.org/10.3390/polym13040570.
8. Wu H., Zhu L.N., Yue W., et al. Wear-resistant and hydrophobic characteristics of PTFE/CF composite coatings. Progress in Organic Coatings. 2019;128:90–98. https://doi.org/10.1016/j.porgcoat.2018.12.013.
9. Vasilev A.P., Struchkova T.S., Lazareva N.N., et al. Effect of molybdenum disulphide and carbon fibers on the properties and structure of polymer composite materials based on polytetrafluoroethylene. Arctic and Subarctic Natural Resources. 2022;27(4):618–630. https:// doi.org/10.31242/2618-9712-2022-27-4-618-630. (In Russ.)
10. Kadykova Y.A. A structural polymeric composite material reinforced with basalt fiber. Russian Journal of Applied Chemistry. 2012;85:1434–1438. https://doi.org/10.1134/S1070427212090212.
11. Danilova S.N., Okhlopkova A.A., Gavrilyeva A.A., et al. Wear resistant polymer composite materials with improved interfacial interaction in the system “polymerfiber”. Vestnik NEFU. 2016;5(55):80–92. (In Russ.)
12. Bednarowski D., Bazan P., Kuciel S. Enhancing strength and sustainability: evaluating glass and basalt fiber-reinforced biopolyamide as alternatives for petroleum-based polyamide composite. Polymers. 2023;15(16): 3400. https://doi.org/10.3390/polym15163400.
13. Chukov D.I., Stepashkin A.A., Maksimkin A.V., et al. Investigation of structure, mechanical and tribological properties of short carbon fiber reinforced UHMWPEmatrix composites. Composites Part B: Engineering. 2015; 76:79–88. https://doi.org/10.1016/j.compositesb.2015.02.019.
14. Cui W., Yang S., Zhang X., et al. High wear resistance of ultralow-wear polyethylene with different molecular weights under different contact pressure. Tribology Letters. 2022;70(2):51. https://doi.org/10.1007/s11249-022-01595-2.
15. Zhornik V.I., Kovaliova S.A., Grigoryeva T.F., et al. Formation of structure of highly filled UHMWPE composites under conditions of intensive mechanical activation for radiation protective materials. Mechanics of Machines, Mechanisms and Materials. 2019;(4):70–78. (In Russ.)
16. Guo Z., Xu R., Xue P. Study on preparation of ultrahigh-molecular-weight polyethylene pipe of good thermalmechanical properties modified with organo-montmoril- lonite by screw extrusion. Materials. 2020;13(15):3342. https://doi.org/10.3390/ma13153342.
17. Deberdeev T.R., Andrianova K.A., Amirova L.M. Overview of development and application ways of polymer fiber composite materials. Izvestiya vysshikh uchebnykh zavedenii. Teknologiya tekstil’noi promyshlennosti. 2021;6(396):5–13. https://doi.org/10.47367/0021-3497_2021_6_5. (In Russ.)
18. Ushkanov A.A., Lazareva N.N., Okhlopkova A.A., Vasilev A.P. Research of polymer composite materials based on polytetrafluoroethylene and carbon fibers. Polzunovskiy Vestnik. 2023;(4):223–229. https://doi.org/10.25712/ASTU.2072-8921.2023.04.028. (In Russ.)
19. Vadivel H.S., Golchin A., Emami N. Tribological behaviour of carbon filled hybrid UHMWPE composites in water. Tribology International. 2018; 124:169–177. https://doi.org/10.1016/j.triboint.2018.04.001.
20. Burov A.E. Models of failure of fibrous composites. Vestnik of SibGAU. 2008;3(20):133–138. (In Russ.)
21. Ekimenko A.N. The organosilanes prospects in thermoplastic composites with vegetable fillers. Plasticheskie Massy. 2018;(1-2):28–33. (In Russ.)
22. Wang B., Yu S., Mao J., et al. Effect of basalt fiber on tribological and mechanical properties of polyetherether-ketone (PEEK) composites. Composite Structures. 2021;266:113847. https://doi.org/10.1016/j.compstruct. 2021.113847.
23. Vasilev A.P., Struchkova T.S., Okhlopkova A.A., Alekseev A.G. Study of the influence of carbon and basalt fibers with ultradisperse PTFE on the tribological properties of polytetrafluoroethylene. South-Siberian Scientific Bulletin. 2020;(1):89–95. (In Russ.)
24. Krasnov A.P., Naumkin A.V., Yudin A.S., et al. Nature of initial acts of friction of ultrahigh molecular weight polyethylene with steel surface. Journal of Friction and Wear. 2013;34(2):120–128. https://doi.org/10.3103/S1068366613020074.
25. Liu H., Luo B., Shen S., Li L. Design and mechanical tests of basalt fiber cloth with MAH grafted reinforced bamboo and poplar veneer composite. European Journal of Wood and Wood Products. 2019;77:271–278. https://doi.org/10.1007/s00107-018-1378-9.
26. Kim H.I., Hang W., Choi W.-Ki, et al. Effects of maleic anhydride content on mechanical properties of carbon fibers-reinforced maleic anhydride-grafted-poly-propylene matrix composites. Carbon Letters. 2016;20:39– 46. https://doi.org/10.5714/CL.2016.20.039
Review
For citations:
Danilova S.N., Okhlopkova A.A., Okoneshnikova A.V. Development of composite materials based on UHMWPE using carbon and basalt fibers. Arctic and Subarctic Natural Resources. 2024;29(4):661-674. (In Russ.) https://doi.org/10.31242/2618-9712-2024-29-4-661-674