The effect of low temperature on the supermolecular structure of the material of welded joint in polymer pipes
https://doi.org/10.31242/2618-9712-2019-24-4-14
Abstract
The supramolecular structure of a welded joint of polypropylene pipes, made into a bell at positive and negative ambient temperatures, is investigated. The hypothesis put forward by the authors is confirmed that, regardless of the ambient temperature when welding polypropylene, the structure of the seam under the surface layer of the welded joint becomes spherical like that of the main polymer material. When welding polymeric materials at low ambient temperatures, the effect of conductive heat removal on the formation of the supramolecular structure of the heat-affected zone of the welded joint is especially pronounced due to the low coefficient of thermal conductivity. The structure of welded joints of polypropylene pipes was studied using a scanning electron microscope. It was shown that the nature and size of supermolecular formations in the structure of welded joints made in the open air at a temperature of –30 °C according to the welding technology developed and patented in the Institute of oil and gas problems SB RAS are identical with the structure obtained at positive ambient temperatures. It is shown that in the heat affected zone of the welded joint of polypropylene pipes, welded even at about 0 °C, regions with a destructured supermolecular structure found. The directions of further research are given.
Keywords
About the Authors
Aleksandr Innokentevich GerasimovRussian Federation
Gerasimov Aleksandr Innokentevich, candidate of technical sciences, leading researcher, Institute of Oil and Gas Problems SB RAS, 20 Avtodorozhnaya st., Yakutsk, 677007, Russia, https://orcid.org/0000-0003-4114-9955, gerasimov2509@rambler.ru;
Gleb Vladimirovich Botvin
Russian Federation
Botvin Gleb Vladimirovich, leading engineer, Institute of Oil and Gas Problems SB RAS, 20 Avtodorozhnaya st., Yakutsk, 677007, Russia, https://orcid.org/0000-0001-7834-8144, gleb-0379@mail.ru
Elena Viktorovna Danzanova
Russian Federation
Danzanova Elena Viktorovna, candidate of technical sciences, senior researcher, Institute of Oil and Gas Problems SB RAS, 20 Avtodorozhnaya st., Yakutsk, 677007, Russia, https://orcid.org/0000-0002-3445-0961, dhv4071@mail.ru.
References
1. Perepelkin V.P. Polypropylene, its properties and processing methods. Leningrad: LDNTP, 1963. 256 p.
2. Tudriy E.V., Galkina I.V., Sobanov A.A., Galkin V.I. Fiziko-khimiya polimerov: uchebno-metodicheskoye posobiye. Kazan’: Kazan. Univ, 2015. 45 p.
3. Baygaliyev B.E., Chernoglazova A.V., Temnikova S.V., Shchelchkov A.V., Timerbulatova I.R., Kalmykov P.E. Issledovaniye vozmozhnosti zameny teploizolyatsionnykh trub s metallicheskimi elementami na truby iz polisul’fona // Bulletin of Kazan Technological University. 2013. Vol. 16, N. 10. P. 96–98.
4. Gureyev V.M., Ermakov A.M., Gel’manov R.R., Kalimullin R.R. Razrabotka perspektivnykh otopitel’nykh priborov iz nemetallicheskikh materialov Energetika Tatarstana. 2010. N. 3 (19). P. 59–62.
5. Pronichev D.V., Trykov YU.P., Gurevich L.M., Slautin O.V. Issledovaniye teploprovodnosti sloistykh metallicheskikh kompozitov // Izvestiya Volgogradskogo gosudarstvennogo tekhnicheskogo universiteta. 2007. N. 5 (31). P. 34–36.
6. Thermal conductivity of air depending on temperature and pressure. URL: http://thermalinfo.ru/svojstva-ga- zov/gazovye-smesi/teploprovodnost-vozduha-v-zavisimosti-ot-temperatury-i-davleniya, (accessed 01.11.2018).
7. Gerasimov A.I. Nekotoryye voprosy svarnogo soyedineniya polimernykh materialov // Nauka i innovatsii v XXI veke: Aktual’nyye voprosy, otkrytiya i dostizheniya: sb. statey XI Mezhdunar.nauchn.-prakt. konf. CH.1. – Penza: MTSNS «Nauka i prosveshcheniye». 2018. P. 118–122.
8. Komarov G.V. Soyedineniye detaley iz polimernykh materialov: Uchebnoye posobiye. SPb.: Professiya, 2006. 592 p.
9. Zaytsev K.I., Matsyuk L.N., Bogdashevskiy A.G. Svarka polimernykh materialov: Spravochnik. M.: Mashinostroyeniye, 1988. 312 p.
10. Botvin G.V., Danzanova E.V., Gerasimov A.I. Metodika ispytaniy na prochnost’ svarnogo soyedineniya polipropilenovykh trub // Zavodskaya laboratoriya. Diagnostika materialov. 2017. Vol. 83, N. 9. P. 70–72.
11. Set of Rules SP 40-101-96 Svod pravil po proektirovaniyu i montazhu truboprovodov iz polipropilena
12. «Random sopolimer». M.: GUP TsPP, 1997. 33 p.
13. Industrial Construction Standards VSN 003-88. Stroitel’stvo i proyektirovaniye truboprovodov iz plastmassovykh trub. M.: Rotaprint VNIIST, 1990. 107 p.
14. Starostin N.P., Gerasimov A.I., Botvin G.V., Danzanova E.V. Svarka polipropilenovykh trub pri otritsatel’nykh temperaturakh // Stroitel’stvo unikal’nykh zdaniy i sooruzheniy. 2017. N. 4 (55). P. 7–18. doi: 10.18720/CUBS.55.1.
15. Rambidi N.G. Struktura polimerov – ot molekul do nanoansambley: Uchebnoye posobiye. Dolgoprudnyy: Izdatel’skiy Dom «Intellekt», 2009. 264 p.
16. Kargin V.A., Slonimskiy G.L. Kratkiye ocherki po fiziko-khimii polimerov / M.: Khimiya, 1967. 232 p.
17. Zhirnov A.E., Arzhakov M.S. Struktura polimerov. Metodicheskaya razrabotka dlya teoreticheskogo kursa i laboratornykh rabot po vysokomolekulyarnym soyedineniyam. M.: MGU, 2013. 41 p.
18. Kuchmenova L.KH. Termicheskiye svoystva polimer-polimernykh kompozitov na osnove polipropilena: Kand diss. Nal’chik, 2014. 125 p.
19. Spinaa R., Spekowiusb M., Hopman C. Simulation of crystallization of isotactic polypropylene with different shear regimes // Thermochimica Acta. 2018. Vol. 659. P. 44–54. https://doi.org/10.1016/j.tca.2017.10.023
20. Ammosova O.A. Chislennoye modelirovaniye teplovogo protsessa svarki polietilenovykh trub pri nizkikh temperaturakh. Kand diss. Yakutsk, 2009. 126 p.
21. Starostin N.P., Ammosova O.A. Simulation of the thermal process of butt welding of polyethylene pipes at low temperatures // Journal of Engineering Physics and Thermophysics. 2016. Vol. 89, N. 3. P. 714–720. https:// doi.org/10.1007/s10891-016-1430-8
22. Starostin N.P., Vasilieva M.A., Ammosova O. A. Developing the process of welding of polypropylene pipes into a socket at low temperatures. Mechanics, resource and diagnostics of materials and structures (MRDMS-2016) // Proceedings of the 10th International Conference. – AIP Publishing. 2016. N. 1785, 040082. https://doi.org/10.1063/1.4967139
23. Vasilieva M.A., Starostin N.P. Modeling of thermal process of preheating polyethylene pipe and coupling with replaceable nozzles for socket welding at low temperatures // Proceedings of the 12th International Conference on Mechanics, Resource and Diagnostics of Materials and Structures (MRDMS-2018). – AIP Conference Proceedings. 2018. N. 2053. 040100. https://doi. org/10.1063/1.5084538
24. Gerasimov A.I., Danzanova E.V., Botvin G.V. Research methods of strength of weld seam of polymer pipes // Proceedings of the 12th International Conference on Mechanics, Resource and Diagnostics of Materials and Structures (MRDMS-2018). – AIP Conference Proceedings. 2018. N. 2053. 030018. https://doi. org/10.1063/1.5084379
25. Starostin N.P., Gerasimov A.I., Danzanova E.V., Botvin G.V., Andreyev B.I. Effektivnost’ elektromuftovoy svarki polietilenovykh trub pri nizkikh temperaturakh okruzhayushchego vozdukha // Svarochnoye proizvodstvo. 2017. N. 11. P. 47–49.
26. Danzanova E.V. Svarka polietilenovykh trub dlya gazoprovodov pri yestestvenno nizkikh temperaturakh: Kand. diss. M., 2012. 143 p
Review
For citations:
Gerasimov A.I., Botvin G.V., Danzanova E.V. The effect of low temperature on the supermolecular structure of the material of welded joint in polymer pipes. Arctic and Subarctic Natural Resources. 2019;24(4):152-160. (In Russ.) https://doi.org/10.31242/2618-9712-2019-24-4-14