Preview

Arctic and Subarctic Natural Resources

Advanced search

Unique diamond from the Nyurbinskaya pipe (Nakyn kimberlite field, West Yakutia, Russia)

https://doi.org/10.31242/2618-9712-2020-25-2-3

Abstract

For the first time in the world, a unique diamond has been discovered, with a smaller diamond freely moving in its cavity. The crystals were studied in detail by X-ray microtomography, which allowed us to build three-dimensional models of them, to establish in detail the morphological features of both the host and the prisoner minerals, and to determine the weight of each of them. On diametrically opposite surfaces of the host diamond, there are two through channels that lead to the cavity in which the internal diamondprisoner is located. The channels contain barite, and one of the channels is hermetically sealed with this mineral. At the entrance to the cavity, both channels are narrow and have a diameter of about 0.1 mm. The morphology of the internal walls of the cavity approximates the morphology of the surface of the internal diamond. According to the results of infrared spectroscopy, the diamond has a high content of structural nitrogen impurity 1,250 at. ppm. Integral volume mapping was performed using Raman confocal spectroscopy, which resulted in a layer-by-layer reconstruction of the internal structure of the diamond. Luminescence studies using a laser with a long excitation wave of 337 nm revealed a uniform pink-lilac glow in both diamonds.

About the Authors

D. V. Konogorova
NIGP PJSC «ALROSA»; Lomonosov Moscow State University
Russian Federation

KONOGOROVA Diana Viktorovna, senior researcher, Geo-Scientific Research Enterprise

16 Chernyshevskoe shosse, Mirny, 678170, Republic of  Sakha (Yakutia)



O. E. Kovalchuk
NIGP PJSC «ALROSA»
Russian Federation

KOVALCHUK Oleg Evgenievich, deputy director, Geo-Scientific Research Enterprise

16 Chernyshevskoe shosse, Mirny, 678170, Republic of  Sakha (Yakutia)



L. D. Bardukhinov
NIGP PJSC «ALROSA»
Russian Federation

BARDUKHINOV Leonid Daniilovich, head of the  laboratory, Geo-Scientific Research Enterprise

16 Chernyshevskoe shosse, Mirny, 678170, Republic of  Sakha (Yakutia)



References

1. Garanin V.K. Mineralogy of kimberlites and related rocks of the diamond-bearing provinces of Russia in connection with their Genesis and search. Diss. ... doct. geol.-min. sciences. M.: Moscow state University, 2006.

2. Orlov Yu.L. Mineralogy of diamond. Moscow: Nauka, 1984. 264 р.

3. Kostrovitsky S.I., Spezius Z.V., Yakovlev D.A., von der Flaass G.S., Suvorova L.F., Bogush I.N. Atlas of indigenous diamond deposits of the Yakut kimberlite province. Mirny: ALROSA, 2015. 480 р.

4. Shatalov V.I., Grahanov S.A., Egorov A.N., Safyannikov Yu.V. Geological structure and diamond content of ancient placers of diamonds of the Nakyn kimberlite field of the Yakut diamondiferous province // Bulletin of the Voronezh University. Geology. 2002. No. 1.

5. Zaitsev A.M. Optical properties of diamond: A data handbook. Berlin; Heidelberg: Springer, 2001. 502 р.

6. Harkiv A.D., Zinchuk N.N., Kryuchkov A.I. Indigenous diamond deposits of the world. Moscow: Nedra, 1998. 554 p.

7. Boyd S.R., Kiflawi I., Woods G.S. The relationship between infrared absorption and the A defect concentration in diamond // Phil. Mag., B. 1994. Vol. 69. P. 1149–1153.

8. Boyd. S.R., Kiflawi I., Woods G.S. Infrared absorption by the B nitrogen aggregate in diamond // Phil. Mag., B. 1995. Vol. 72. P. 351–361.

9. Field J.E. The Properties Natural and Synthetic Diamond. London: Academic Press, 1992.

10. Welbourn C.M., Saito S., Fujimory N., Fukunaga О., Kamo M., Kobashi K., Yoshikawa M. In Advances in New Diamond Science and Technology. Tokyo, 1994. 327 р.

11. Vasiliev E.A. Planar optically active centers of diamonds as indicators of diamond formation conditions. Abstract. diss ... cand. geol.-minю sciences. SPb, 2007. 21 р.

12. Kriulina G.Yu. Constitutional characteristics of diamond from the deposits of the Arkhangelsk and Yakut diamond-bearing provinces. Author of the diss. ... сand. geol.-min. Moscow, 2012. 24 р.

13. Kriulina G.Yu., Vasiliev E.A., Garanin V.K. Structural defects in diamonds of the Arkhangelsk and Yakut diamond-bearing provinces // Collection of publications on the results of the III and IV annual scientific readings named after G. P. Kudryavtsev / Institute of applied Mineralogy, 2010. P. 93–103.

14. Blinova G.K. Structural additives as indicators of the mechanism of growth of natural diamond crystals // Dokl. AN SSSR. 1987. Vol. 294, No. 4. Р. 868–871

15. Vince V.G. Optically active defects in diamondregularities of formation and mutual transformation. Autoref. dis. ... doctor of physical and mathematical Sciences. Barnaul, 2011. 40 Р.

16. Vince V.G., Eliseev A.P. Influence of growing conditions on the spectral characteristics of synthetic diamonds of type Ib // Perspective materials. 2009. No. 6. P. 36–42.

17. Vince V.G., Eliseev A.P. Influence of annealing at high pressures and temperatures on the defect-impurity structure of natural diamonds // Perspective materials. 2010. No. 1. P. 49–58.

18. Beskrovanov V.V. Ontogeny of diamond. Novosibirsk: Nauka, 2000. 264 Р.

19. Kukharenko A.A. Almazy Ural. M.: Gosgeoltehizdat, 1955. 514 Р.

20. Khokhryakov A.F. Experimental study of the formation of rounded diamond crystals // Bulletin of the Russian Academy of Sciences. 2000. Vol. 1, Iss. 15, No. 5. P. 80–88.

21. Chepurov A.I., Fedorov I.I., Sonin V.M. Experimental modeling of diamond formation processes. Novosibirsk: publishing house of SB RAS, 1997. 197 Р.

22. Kulakova I.I., Pushkin A.N., Rudenko A.P., Shturman V.L. Investigation of the catalytic oxidation of diamonds in connection with the issues of their growth-dissolution in natural conditions // Trudy СNIGRI. M.: 1980. Issue 153. P. 57–63.

23. Litvin Yu.A., Bezrukov G.N. On the growth of artificial diamond crystals // Dokl. AN SSSR. 1968. Vol. 181, No. 5. P. 1123–1125.

24. Krasnova N.I., Petrov T.G. Genesis of mineral individuals and aggregates. Nevsky courier, 1997. 228 р.

25. Punin Yu.O. Splitting of crystals // ZVMO. 1981. CH. 110, Vol. 6. P. 666–686.


Review

For citations:


Konogorova D.V., Kovalchuk O.E., Bardukhinov L.D. Unique diamond from the Nyurbinskaya pipe (Nakyn kimberlite field, West Yakutia, Russia). Arctic and Subarctic Natural Resources. 2020;25(2):47-57. (In Russ.) https://doi.org/10.31242/2618-9712-2020-25-2-3

Views: 125


Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 License.


ISSN 2618-9712 (Print)
ISSN 2686-9683 (Online)